Screening of Analgesic Drug - A Study



INTRODUCTION

          Pain is an unpleasant sensory and emotional experience associated with actual and potential tissue damage. Various types of pain are seen in humans, for example, somatic pain arising from the skin, muscles, joints, ligaments and bones, visceral pain, referred pain, neuropathic pain, cancer pain etc.

          Chemical mediators of pain are numerous. These mediators come from sources intrinsic to the neuron including various neurotransmitters such as 5HT and substance P and extrinsic to the nervous system, including substances from inflammatory/immune cells and red blood cells such as prostaglandins, kinins, cytokines, chemokines and ATP that are released following injury to the tissue.

Pain and Nociception
          Pain is produced by the excitation of particular receptors, the nociceptors or of their afferent fibres. These remarkable cells respond to a broad spectrum of physical (heat, cold and pressure) or chemical noxious stimuli. In general, perception of noxious stimuli is termed as nociception. Nociception is not exactly same as pain; pain is a subjective experience and includes a strong effective component, whereas nociception lacks affective component. Most of the afferent fibres that are excited by noxious stimuli are nonmyelinated C-fibres with low conduction velocities (<1 m/s), known as C-polymodal nociceptors (PMN), and other fibres are fine myelinated (Ad) fibres with rapid conduction.

Animal Models
          Animal tests used in the search for new analgesics are designed as models for the treatment of pathological pain in man, but they usually differ from the original in that the test drug is given before the noxious stimulus (mechanical, thermal, chemical and electrical and electrical types of stimuli) in the animal models. Hence, these tests only measure the power of a drug to increase the threshold of minimal required to elicit pain or nociceptive response.

Haffner’s Tail Clip Method
          In this method mechanical stimulus is applied. This method is highly sensitive for centrally acting drugs.

Procedure
          Male mice weighing 18 to 25 g are used. An artery clip is placed at the root of the tail of the mice to apply noxious stimulus. A quick response of the animal is seen as biting the clip or tail, where clip has been placed. The time (reaction time) between application of the clip and response is noted by a stopwatch. For testing analgesic activity, test compounds are administered subcutaneously or orally. After 15, 30 or 60 min, same procedure is repeated and reaction time is measured. For evaluations of analgesic drugs, cut off time is determined i.e. average reaction time plus 3 times the standard deviation of the combined latencies of the control mice at all time periods. Reaction time of the test animals, greater than the cut off time denotes a positive response indicating analgesic activity.

Hot Plate Method
          Hot plate method has been widely used to evaluate opioids analgesics.

Procedure
          Mice weighing 18 to 22 g are used. Animals are placed on the hot plate, which consists of electrically heated surface. Temperature of the hot plate is maintained at      55-560C. Responses such as jumping, withdrawal of the paws and licking of the paws are seen. The time period (latency period) when animals are placed and until responses occur is recorded by a stopwatch. Test compounds are administered orally or subcutaneously and latency or latency period is recorded after 20, 60 and 90 min. These values are compared with the values before administration of the test drug.

Radiant Heat Method
          Mice weighing 18 to 22 g are used and placed into small cages leaving the tail exposed mouse tail is held gently by the observer. A light beam is focused (exerting radiant heat) to the proximal third of the tail. The mouse tries to pull the tail away and rotates the head, this reaction is known as escape reaction. The reaction is noted for 6 sec by the observer. The test drug and standard are administered either orally and subcutaneously. Same procedure is performed and reaction time is noted after 30, 60 and 120 min.

          At each time interval those animals that show higher reaction time than the time before drug administration are regarded as positive. Percentages of positive animals are counted for each time interval and each dose. ED values of test compounds can be calculated codeine, pethidine and morphine are used as standard.

Tail Warm Water Immersion Method
          Young female Wistar rats weighing 170 to 210 g are used. Rats are placed into separate cages and tail hangs out freely. The distal 5 cm part of the tail is marked which is immersed (max upto 15 sec) in a cup filled with warm water (temp 550c). A tail withdrawal reflex is seen within a few seconds. This reaction time is noted by stopwatch. Normal reaction time is 1 to 5.5 sec. The test substances are given orally or subcutaneously and reaction time is recorded after 0, 5, 1, 2, 3, 4 and 6 h.

          A withdrawal time of more than 6 sec in test animals denotes positive analgesic response of the test drug.

Tooth Pulp Electrical Stimulation Method
          Rabbits weighing 2 to 3 kg are used and anesthesia is given with thiopental in the doses of 15mg/kg intravenously. Using dental drill tooth pulp chambers  are exposed close to the two front upper incisors. Clamping electrodes are placed into the drilled holes. After 30 min, electrical stimulus is applied by rectangular current (frequency 50 Hz) upto 1 sec. Current is started with 0.2 mA and increased until animal starts licking and a threshold is determined at least 3 times in each animal. Animal serves as its own control. Test compound is administered orally or intravenously. After 15, 30, 60 and 120 min threshold current is measured and compared with the threshold current prior to drug administration.

Monkey Shock Titration Test
          The monkey shock titration test is used for final evaluation of a new compound as analgesic.

Procedure
          The monkeys are seated in restraining chairs, by a Coulbourn Instrument Programmable Shocker, electrical current is delivered through electrodes, which are coupled to two test tube clamps attached to a shaved portion of tail. The current ranges from 0-4 mP through 29 progressive steps. The monkey presses a bar to interrupt the shock. For each monkey, a stable baseline shock level is recorded. After 24h drug is administered and shock titration activity is measured according to a change in maximum level of median shock intensity for drug as compared to control levels.

Formalin Test
          This model is a chronic pain model and highly sensitive for opioid-like drugs. Animals show two phases of nociceptive behavior in formalin test involving 2 different stimuli. The first (early) phase starts immediately after injection of formalin and last for 3-5 min. This occurs due to chemical stimulation  of nociceptors causing C-fibre activation. Second (late) phase starts after 10-15 min of formalin injection and lasts for 20-40 min. This phase appears due to combination of an inflammatory reaction in the peripheral tissue and functional changes in the dorsal horn of the spinal cord. The C-fibre barrage initiates functional changes during the early phase. Nonsteroidal anti-inflammatory drugs are effective in second phase, while the first phase remains unaffected.

Procedure
          Male Wistar rats weighing between 180 and 300g are used. In the dorsum of front paw of the animal 0.05ml of 10% formalin is injected subcutaneously. Each animal is placed into separate cage for observation of pain responses in early and late phases. These responses are elevation or favouring of the paw or excessive licking and biting of the paw. Scoring of these pain responses is done according to a pain scale. After administration of the test drug, again scoring is done after 30, 60 min for comparison. If both paws of the animal are allowed to rest on the floor with no obvious of the injected paw, this is taken as a positive analgesic response.

Randall Selitto Test
          Inflammation increases the sensitivity to pain and decreases pain threshold. In Randall Selitto test, inflammation is induced by Brewer’s yeast. After that, pressure is applied to inflamed area to increase the intensity of pain.

Procedure
          Male Wistar rats are used, divided into two groups – test and control. Test agents an administered in test group and vehicle is administered in control group animals. After 15 – 30 min, 0.1 ml of Brewer’s yeast (20% suspension) in distilled water is injected subcutaneously into the plantar surface of the left hind paw of the rat. After 3 h, using a special apparatus (Randall Selittol Apparatus) pressure is applied to the plantar surface of the rat’s foot a constant rate until animal struggles or squeals. In both the groups each animal is test for its control pain threshold for comparison in between the groups. Animal, which is showing control pain threshold greater than 80g is eliminated.
Neuropathic Pain Model
          Male Sprague – Dawley rats are used and anaesthetized with 4% halothane. A local incisic is given and sciatic nerves of both legs are exposed at the level of midthigh. Chromic g sutures 4-0 are tied loosely with a square knot around the right sciatic nerve. Left scial nerve is just mobilized. Incisions are closed layer to layer. During the next days animal show a mild aversion of the affected paw and foot drop. The thermal nociceptive threshold of hind paws is measured in each animal. For this, rats are placed beneath a transpare plastic cage upon a raised glass plate such that a halogen projector lamp could be placed below it. Lamp (source of radiant heat) is focused at the planter area of one hind paw. As soon as heat is applied a withdrawal response of hind paw is measured in each animal. After 7 – 8 days, test drug and vehicle are injected intrathecally in test and control group respectively. Paw withdrawal latency (PWL) of hind paws is recorded before and after 5, 15, 30, 60 and 90 min of drug and vehicle administration. PWL which was the maximum during the first 30 min after drug or vehicle injection is called maximum PWL of the control side (left side) from the maximum PWL of the affected side (right side). For evaluation of drug effects in hyperesthetic rats, the dose is plotted against the change in DS (postdrug difference score minus predrug  difference scor).
          A novel behavioural model of neuropathic pain disorders has also been produced in rats by partial sciatic nerve injury.
          Some other models of pain include electrical stimulation of tail and mechanical visceral pain model.

IN VITRO METHODS
          Identification of several types of opioid  receptors is the brain has allowed to perform in vitro binding tests to study the action of central analgesics. Various new receptors have been identified by using in vitro methods as therapeutic targets for the treatment of pain, especially neuropathic and cancer pain such as receptors for nociceptin, vasoactive intestinal peptide, cannabinoids and vanilloid receptors. Agonists and antagonists for these receptors are being evaluated for clinical use.

3H – Naloxone Binding Assay
          Opiate agonists and antagonists have ability to displace radio labeled naloxone that is a potent narcotic antagonist. 3H-Nsloxone- binding assay is developed to classify analgesics as agonists, mixed agonist-antagonist and antagonists. The basic principle of this assay is to determine IC50 values for 3H-Naloxone in the presence of absence of Na+.

Procedure
          Male Wistar rats are decapitated and their brains are removed. Whole brains without cerebella are homogenized in 50 volumes of ice-cold 0.05 N tris buffer with a tissue homogenizer centrifugation of homogenate is done at 40000g for 15min. Pellet is resuspended in buffer and recentrifuged at 40000g. After this, the final pellet is resuspended in freshly prepared 0.05 M tris buffer. Finally, tissue concentration in the assay becomes 10mg/ml.

          In test tubes a mixture is prepared, which consists of 310 ml H2O 20ml 5 mM dextrophan (total binding) or 5mM levorphanol (nonspecific binding), 50ml 2 M NaCl or H2O, 50ml 0.05M Tris buffer, pH7.7, 20ml drug or vehicle, 50ml 3H-Naloxone and 500ml tissue suspension. The tubes are incubated for 30 min at 370c. Vacuum filtration through Whatman GF B filters is done to stop the assay and washing is performed at least 3 times with ice-cold 0.05 M Tris buffer, pH7.7. The filters are then counted in 10ml of Liquiscint liquid scintillation cocktail. Difference between binding in the presence of 0.1 mM dextrorphan and 0.1mM levorphanol is known as stereospecific binding.

          Specific binding is around 1% of the total added ligand and 50% of the total bound ligand in the absence of Na+ and 2% of the total added ligand and 65% of the total bound ligand in the presence of Na+ (100mM). An increase in specific binding denotes an increase in binding.
          To evaluate analgesic activity, data are converted into % stereospecific 3H-Naloxone binding displaced by the test drug. Determination of IC50 is done by using computer derived log probit analysis. IC50 is  used to calculate sodium shift. Opioid agonists show high sodium shifts, antagonists show low shift and mixed opioid agaonists antagonists show medium sift data are analyzed by a computer program.

Opiate Receptor Binding Assay
          Opioid drugs exert their analgesic effects mainly through m opioid receptors.3H-dihydromorphine is highly selective for m receptors. The compounds that inhibit binding of 3H-dihydromorphine in a synaptic membrane preparation from rat brain can be identified  by this assay.


Procedure
          Male Wistar rats are used. Animals are sacrificed by decapitation. Whole brains without cerebella are removed, weighed and homogenized in 30 volumes of ice cold 0.05 M Tris buffer, pH 7.7. Centrifugation of homogenate is performed at 48000g for 15 min and pellet is resuspended in the same volume of buffer.  This homogenate is incubated to remove the endogenous opiate peptides and centrifuged again. The final pellet is resuspended in 50 volumes of 0.05 M Tris buffer.

          In test tubes a mixture consisting of 1850 ml tissue suspension, 80ml distilled water, 20 ml vehicle or levallorphan or appropriate concentration of drug and 50ml 3H-dihydromorphine is prepared. Then incubation is performed for 30 min at 250c. The assay is stopped by vacuum filtration through Whatman GF/B filters, which are washed twice with 5ml of 0.05 M Tris buffer. Filters are placed into scintillati vials with 10ml liquiscient scintillation cocktail and counted. Specific binding is the difference between total binding and binding in the presence of 0.1mM levallorphan. At each drug concentration, IC50 values are calculated from the percent specific binding.


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